IHTM40040 | Procedures for dealing with an application for clearance: is a certificate appropriate?
From HM Revenue & Customs · Inheritance Tax Manual
A certificate is appropriate where
You can issue a certificate where
tax would be payable if the minimum taxable threshold were exceeded
a relief covers the tax otherwise chargeable.
You can also issue a certificate where no tax is payable because of exempt gifts
You cannot issue a certificate where the property is not chargeable to tax at all (IHTM04141), for example because of the surviving spouse exemption (IHTM04341) available under IHTA84/Sch6Para2. You should also not issue certificates for lifetime transfers (IHTM40011) that are chargeable to tax when made unless the person who made the transfer is now dead and full details of the estate have been received.